Direct allylic C–H alkylation of enol silyl ethers enabled by photoredox–Brønsted base hybrid catalysis
Author:
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Link
http://www.nature.com/articles/s41467-019-10641-y.pdf
Reference36 articles.
1. Stork, G. & Hudrlik, P. F. Isolation of ketone enolates as trialkylsilyl ethers. J. Am. Chem. Soc. 90, 4462–4464 (1968).
2. Kan, S. B. J., Ng, K. K. H. & Paterson, I. The impact of the Mukaiyama aldol reaction in total synthesis. Angew. Chem. Int. Ed. 52, 9097–9108 (2013).
3. Matsuo, J. & Murakami, M. The Mukaiyama aldol reaction: 40 years of continuous development. Angew. Chem. Int. Ed. 52, 9109–9118 (2013).
4. Magnus, P., Lacour, J., Evans, P. A., Roe, M. B. & Hulme, C. Hypervalent iodine chemistry: new oxidation reactions using the iodosylbenzene−trimethylsilyl azide reagent combination. Direct α- and β-azido functionalization of triisopropylsilyl enol ethers. J. Am. Chem. Soc. 118, 3406–3418 (1996).
5. Tietze, L. F. Domino Reactions: Concepts for Efficient Organic Synthesis (Wiley, Weinheim, 2014).
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