Abstract
AbstractThe exploration of highly efficient processes to convert renewable biomass to fuels and value-added chemicals is stimulated by the energy and environment problems. Herein, we describe an innovative route for the production of methylcyclopentadiene (MCPD) with cellulose, involving the transformation of cellulose into 3-methylcyclopent-2-enone (MCP) and subsequent selective hydrodeoxygenation to MCPD over a zinc-molybdenum oxide catalyst. The excellent performance of the zinc-molybdenum oxide catalyst is attributed to the formation of ZnMoO3 species during the reduction of ZnMoO4. Experiments reveal that preferential interaction of ZnMoO3 sites with the C=O bond instead of C=C bond in vapor-phase hydrodeoxygenation of MCP leads to highly selective formations of MCPD (with a carbon yield of 70%).
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry
Reference25 articles.
1. Huber, G. W., Iborra, S. & Corma, A. Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering. Chem. Rev. 106, 4044–4098 (2006).
2. Shylesh, S., Gokhale, A. A., Ho, C. R. & Bell, A. T. Novel strategies for the production of fuels, lubricants, and chemicals from biomass. Acc. Chem. Res. 50, 2589–2597 (2017).
3. Huber, G. W., Chheda, J. N., Barrett, C. J. & Dumesic, J. A. Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates. Science 308, 1446–1450 (2005).
4. Cao, Z., Dierks, M., Clough, M. T., Daltro de Castro, I. B. & Rinaldi, R. A convergent approach for a deep converting lignin-first biorefinery rendering high-energy-density drop-in fuels. Joule 2, 1118–1133 (2018).
5. Dong, L. et al. Breaking the limit of lignin monomer production via cleavage of interunit. Carbon Carbon Link. Chem. 5, 1521–1536 (2019).
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