Hydrogen bonding template enables remote meta-C–H alkenylation of nitroarenes with electron-deficient alkenes
Author:
Funder
DST | Science and Engineering Research Board
Narodowe Centrum Nauki
NSF | Directorate for Mathematical & Physical Sciences | Division of Chemistry
Publisher
Springer Science and Business Media LLC
Link
https://www.nature.com/articles/s41467-024-51764-1.pdf
Reference33 articles.
1. Tang, R., Li, G. & Yu, J.-Q. Conformation-induced remote meta-C−H activation of amines. Nature 507, 215–220 (2014).
2. Bera, M., Modak, A., Patra, T., Maji, A. & Maiti, D. Meta-Selective Arene C−H Bond Olefination of Arylacetic Acid Using a Nitrile-Based Directing Group. Org. Lett. 16, 5760–5763 (2014).
3. Bag, S. et al. Remote para-C−H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly. J. Am. Chem. Soc. 137, 11888–11891 (2015).
4. Leow, D., Li, G., Mei, T.-S. & Yu, J.-Q. Activation of remote meta-C−H bonds assisted by an end-on template. Nature 486, 518–522 (2012).
5. Yang, G. et al. Pd(II)-Catalyzed meta-C−H Olefination, Arylation, and Acetoxylation of Indolines Using a U-Shaped Template. J. Am. Chem. Soc. 136, 10807–10813 (2014).
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