Increase in global emissions of HFC-23 despite near-total expected reductions

Abstract

AbstractUnder the Kigali Amendment to the Montreal Protocol, new controls are being implemented to reduce emissions of HFC-23 (CHF$${}_{3}$$3), a by-product during the manufacture of HCFC-22 (CHClF$${}_{2}$$2). Starting in 2015, China and India, who dominate global HCFC-22 production (75% in 2017), set out ambitious programs to reduce HFC-23 emissions. Here, we estimate that these measures should have seen global emissions drop by 87% between 2014 and 2017. Instead, atmospheric observations show that emissions have increased and in 2018 were higher than at any point in history (15.9 $$\pm \ 0.9\ {\rm{{Gg}}\ {{{yr}}}^{-1}}$$±0.9Ggyr−1). Given the magnitude of the discrepancy between expected and observation-inferred emissions, it is likely that the reported reductions have not fully materialized or there may be substantial unreported production of HCFC-22, resulting in unaccounted-for HFC-23 by-product emissions. The difference between reported and observation-inferred estimates suggests that an additional ~309 Tg $${{\rm{CO}}}_{2}$$CO2-equivalent emissions were added to the atmosphere between 2015 and 2017.