Abstract
AbstractSupramolecular polymers are formed through non-covalent, directional interactions between monomeric building blocks. The assembly of these materials is reversible, which enables functions such as healing, repair, or recycling. However, supramolecular polymers generally fail to match the mechanical properties of conventional commodity plastics. Here we demonstrate how strong, stiff, tough, and healable materials can be accessed through the combination of two metallosupramolecular polymers with complementary mechanical properties that feature the same metal-ligand complex as binding motif. Co-assembly yields materials with micro-phase separated hard and soft domains and the mechanical properties can be tailored by simply varying the ratio of the two constituents. On account of toughening and physical cross-linking effects, this approach affords materials that display higher strength, toughness, or failure strain than either metallosupramolecular polymer alone. The possibility to combine supramolecular building blocks in any ratio further permits access to compositionally graded objects with a spatially modulated mechanical behavior.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Adolphe Merkle Foundation
Publisher
Springer Science and Business Media LLC
Subject
General Physics and Astronomy,General Biochemistry, Genetics and Molecular Biology,General Chemistry,Multidisciplinary
Cited by
26 articles.
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