Abstract
AbstractIt is important to develop highly active and stable catalysts for high temperature reactions, such as dry reforming of methane. Here we show a La(NiCo)OΔ (LNCO) submonolayer catalyst (SMLC) stabilized by the surface lattice of a perovskite LaCrO3 support and demonstrate a Ni-Co synergistic effect. The submonolayer/support type catalyst was prepared by in-situ hydrogen reduction of a LaNi0.05Co0.05Cr0.9O3 precursor synthesized by a sol-gel method. The LNCO-SMLC is highly active and very stable during a 100 h on stream test at 750 °C under the reaction conditions of dry reforming of methane. The catalyst also shows good anti-coking ability. We found that the synergistic effect between Ni and Co atoms in LNCO-SMLC remarkably improved the thermostability of the catalyst. This work provides a useful concept for designing atomically dispersed catalysts with high thermostability.
Funder
National Natural Science Foundation of China
Publisher
Springer Science and Business Media LLC
Subject
Materials Chemistry,Biochemistry,Environmental Chemistry,General Chemistry
Cited by
7 articles.
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