Highly improved supercapacitance properties of MnFe2O4 nanoparticles by MoS2 nanosheets

Abstract

AbstractManganese ferrite (MnFe2O4) nanoparticles were synthesized via a hydrothermal method and combined with exfoliated MoS2 nanosheets, and the nanocomposite was studied as a supercapacitor. X-ray diffractometry and Raman spectroscopy confirmed the crystalline structures and structural characteristics of the nanocomposite. Transmission electron microscopy images showed the uniform size distribution of MnFe2O4 nanoparticles (~ 13 nm) on few-layer MoS2 nanosheets. UV–visible absorption photospectrometry indicated a decrease in the bandgap of MnFe2O4 by MoS2, resulting in a higher conductivity that is suitable for capacitance. Electrochemical tests showed that the incorporation of MoS2 nanosheets largely increased the specific capacitance of MnFe2O4 from 600 to 2093 F/g (with the corresponding energy density and power density of 46.51 Wh/kg and 213.64 W/kg, respectively) at 1 A/g, and led to better charge–discharge cycling stability. We also demonstrated a real-world application of the MnFe2O4/MoS2 nanocomposite in a two-cell asymmetric supercapacitor setup. A density functional theory study was also performed on the MnFe2O4/MoS2 interface to analyze how a MoS2 monolayer can enhance the electronic properties of MnFe2O4 towards a higher specific capacitance.