Author:
Singh Parminder,Mishra Saumyaranjan,Sahoo Anupam,Patra Srikanta
Abstract
AbstractHerein, we report a magnetically retrievable mixed-valent Fe3O4@SiO2/Pd0/PdIINP (5) nanocomposite system for tandem Suzuki coupling/transfer hydrogenation reaction. The nanocomposite 5 was prepared first by making a layer of $$\hbox {SiO}_{2}$$
SiO
2
on $$\hbox {Fe}_{3}\hbox {O}_{4}\hbox {NP}$$
Fe
3
O
4
NP
followed by deposition of $$\hbox {Pd}^{0}$$
Pd
0
and sorption of $$\hbox {Pd}^{\mathrm{II}}$$
Pd
II
ions successively onto the surface of Fe3O4@SiO2NP. The nanocomposite was characterized by powder XRD, electron microscopy (SEM-EDS and TEM-EDS) and XPS spectroscopy techniques. The mixed-valent $$\hbox {Pd}^{0}/\hbox {Pd}^{\mathrm{II}}$$
Pd
0
/
Pd
II
present onto the surface of nanocomposite 5 was confirmed by XPS technique. Interestingly, the mixed-valent nanocomposite Fe3O4@SiO2/Pd0/PdIINP (5) exhibited tandem Suzuki coupling/transfer hydrogenation reaction during the reaction of aryl bromide with aryl boronic acid (90% of C). The nanocomposite 5 displayed much better reactivity as compared to the monovalent Fe3O4@SiO2/Pd0NP (3) (25% of C) and Fe3O4@SiO2/PdIINP (4) (15% of C) nanocomposites. Further, because of the presence of magnetic $$\hbox {Fe}_{3}\hbox {O}_{4}$$
Fe
3
O
4
, the nanocomposite displayed its facile separation from the reaction mixture and reused at least for five catalytic cycles.
Funder
Council of Scientific and Industrial Research, India
Publisher
Springer Science and Business Media LLC
Cited by
6 articles.
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