Abstract
AbstractIn the present study, Anderson-type polyoxometalate [N(C4H9)4] [FeMo6O18(OH)6] (FeMo6) was immobilized on amino-modified magnetic graphene oxide and employed as a new hybrid catalyst in oxidation of aldehydes to carboxylic acids. The synthesized hybrid catalyst Fe3O4/GO/[FeMo6] was characterized using thermogravimetric analysis (TGA), scanning electron microscopies (SEM), Fourier transform infrared (FT-IR), vibrating sample magnetometry (VSM), energy-dispersive X‐ray analysis (EDX), Raman spectroscopy and inductively coupled plasma atomic emission spectroscopy (ICP-OES). The results indicated that our catalyst was quite active in oxidizing the aldehydes to their corresponding carboxylic acids in the presence of hydrogen peroxide. The synthesized catalyst can be easily separated from the reaction medium and reused for six consecutive runs without a significant reduction in reaction efficiency.
Publisher
Springer Science and Business Media LLC
Reference68 articles.
1. Li, J., Huang, C. Y. & Li, C. J. Deoxygenative functionalizations of aldehydes, ketones and carboxylic acids. Angew. Chem. Int. Ed. Engl. 61, e202112770 (2022).
2. Filipowska, W. et al. On the contribution of malt quality and the malting process to the formation of beer staling aldehydes: A review. J. Inst. Brew. 127, 107–126 (2021).
3. Arinaga, A. M., Ziegelski, M. C. & Marks, T. J. Alternative oxidants for the catalytic oxidative coupling of methane. Angew. Chem. Int. Ed. Engl. 60, 10502–10515 (2021).
4. Siahrostami, S. et al. A review on challenges and successes in atomic-scale design of catalysts for electrochemical synthesis of hydrogen peroxide. ACS Catal. 10, 7495–7511 (2020).
5. Bagheri, A. R. et al. Polyoxometalate-based materials in extraction, and electrochemical and optical detection methods: A review. Anal. Chim. Acta 18, 339509 (2022).
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