Verification of experimental results with simulation on production of few-layer graphene by liquid-phase exfoliation utilizing sonication

Abstract

AbstractGraphene, an extraordinary tow-dimensional carbon nanostructure, has attracted global attention due to its electronic, mechanical, and chemical properties; therefore, there is a need to find out an economical mass production method to produce graphene. In the present research, the aim is to find out optimal conditions for exfoliation of few-layers graphene (FLG) in a water–ethanol green solution. We varied different parameters of the ultrasonic probe like power quantity and time duration of sonication to investigate the effects on the number of graphene layers and density of graphene in the solution. Also, an attempt has been made to predict the acoustic pressure distribution by solving the wave equation in various output powers of the ultrasonic probe (sonotrode) using numerical simulations. The simulations and experimentations verify each other. Concluding that modifying the output power at the same condition will significantly alter the acoustic pressure inside the sonoreactor. The difference in acoustic pressure at 90% output power of our experimentations is much higher than in other conditions. Experimentation results utilizing UV–visible spectra, SEM (Scanning electron microscope), TEM (Transmission electron microscope) images and Raman spectrum indicate that the minimum thickness and maximum exfoliation for these samples are acquired for sonication at 90% of the maximum effective output power of the sonicator being 264 W for 55 min.