Author:
Pokora Mateusz,Paneth Agata,Paneth Piotr
Abstract
AbstractConfinement can result in unusual properties leading to new, exciting discoveries in the nano-realm. One such consequence of confinement at the nanoscale is extremally large isotopic fractionation, especially at sub-van der Waals distances. Herein, on the example of chlorine isotope effects, we show that at conditions of nanoencapsulation these effects may reach values by far larger than observed for the bulk environment, which in the case of nanotubes can lead to practical applications (e.g., in isotopic enrichment) and needs to be considered in analytical procedures that employ nanomaterials.
Funder
Fundacja na rzecz Nauki Polskiej
Publisher
Springer Science and Business Media LLC
Cited by
1 articles.
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1. Non-Covalent Isotope Effects;The Journal of Physical Chemistry Letters;2023-04-12