Abstract
AbstractThe SiO2/TiO2/Nb2O5 material was set by the sol–gel method and was characterized by several techniques through thermogravimetric, spectroscopic, and textural analyzes. For the two synthesized materials, the specific surface area was 350.0 and 494.0 m2 g−1 (SiTiNb-A and SiTiNb-B, respectively). An enhance of the crystalline order with the temperature increase of the thermal treatment was observed. Through X-ray Photoelectron Spectroscopy analysis, the binding energy values for the Ti 2p and Nb 3d levels showed the insertion of Ti and Nb atoms in the silica matrix. The Electron Dispersive Spectroscopy analyses also confirmed the high dispersion of the metals presented on the materials surface. The Thermogravimetric Analysis showed weight loss for the of 37.6% (SiTiNb-A) and 29.7% (SiTiNb-B). The presence of the crystalline phases TiO2-anatase and monoclinic-Nb2O5 in the materials was confirmed through the data obtained by association of powder X-ray Diffraction and FT-Raman. Values obtained from optical band-gap aimed the dependence of the oxides concentration and the calcination temperature. Finally, the pyridine adsorption studies have indicated the presence of Lewis and Brønsted acid sites.
Funder
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
Conselho Nacional de Desenvolvimento Científico e Tecnológico
Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro
Publisher
Springer Science and Business Media LLC
Reference67 articles.
1. Lima, L. F. D., Coelho, C. R., Gomes, G. H. M. & Mohallem, N. D. S. Nb2O5/SiO2 mesoporous monoliths synthetized by sol–gel process using ammonium niobate oxalate hydrate as porogenic agent. J. Sol-Gel Sci. Technhnol. 93, 168–174 (2020).
2. Vrbkova, E. et al. Contribution to MoO3–SiO2 and WO3–SiO2 utilization-active catalysts in jasmine aldehyde, 2-hexyl-1,3-dioxolane and methyllaurate synthesis. React. Kinet. Mech. Catal. 129, 645–658 (2020).
3. Silva, C. N. et al. Characterization of silicon-aluminum-zirconium oxide obtained by the sol-gel process. Quim. Nova 42, 513–521 (2019).
4. Fonseca, B. T. et al. Study of the characteristics, properties and characterization of new SiO2/TiO2/Sb2O5 ternary oxide obtained by the sol–gel process. J. Mater. Sci.: Mater. Electron. 29, 2159–2169 (2018).
5. Umpierres, C. S. et al. Mesoporous Nb2O5/SiO2 material obtained by sol–gel method and applied as adsorbent of crystal violet dye. Environ. Technol. 38, 566–578 (2017).
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