Mg3Al2Si3O12 jeffbenite inclusion in super-deep diamonds is thermodynamically stable at very shallow Earth’s depths

Abstract

AbstractJeffbenite (having the same chemical composition of pyrope, ~ Mg3Al2Si3O12, and also known as TAPP phase) is a mineral inclusion only found in diamonds formed between about 300 and 1000 km depth) and is considered a stable phase in the transition zone (410–660 km depth) and/or in the shallowest regions of the lower mantle (around 660–700 km depth). This rare and enigmatic mineral is considered to be a pressure marker for super-deep diamonds and therefore it has a key role in super-deep diamond research. However, the pressure–temperature stability fields for Mg3Al2Si3O12 jeffbenite is unknown and its actual formation conditions remain unexplored. Here we have determined the thermodynamic pressure–temperature stability field for the jeffbenite Mg-end member and surprisingly discovered that it is stable at low pressure–temperature conditions, i.e., 2–4 GPa at 800 and 500 °C. Thus, Mg3Al2Si3O12 jeffbenite is not the high-pressure polymorph of pyrope and is likely a retrogressed phase formed during the late ascent stages of super-deep diamonds to the surface.