Biogenic synthesis of AgNPs employing Terminalia arjuna leaf extract and its efficacy towards catalytic degradation of organic dyes

Abstract

AbstractIn the present work, we demonstrated the biosynthesis of silver nanoparticles (AgNPs) by highly stable, economic and eco-friendly method using leaf extract of Terminalia arjuna (T. arjuna) and employing as a catalyst for the degradation of methyl orange (MO), methylene blue (MB), congo red (CR) and 4- nitrophenol (4-NP). The biosynthesis of AgNPs was visually validated through the appearance of reddish-brown color and further confirmed by the UV-spectra at 418 nm. The TEM and FE-SEM studies revealed the spherical shape of particles with size ranged between 10–50 nm. Face centered cubic crystalline nature of AgNPs was proved by XRD analysis. The negative value of zeta potential (−21.7) indicated the stability of AgNPs and elemental composition was confirmed by EDS. FT-IR analysis revealed the functional groups present in the plant extract trigger the biosynthesis of AgNPs. The AgNPs exhibited strong degradation of MO (86.68%), MB (93.60%), CR (92.20%) and 4NP (88.80%) by completing the reduction reaction within 20 min. The reaction kinetics followed the pseudo-first-order and displayed k-values (rate constant) 0.166 min−1, 0.138 min−1, 0.182 min−1 and 0.142 min−1 for MO, MB, CR and 4-NP respectively. This study showed an efficient, feasible and reproducible method for the biosynthesis of eco-friendly, cheap and long-time stable AgNPs and their application as potent catalysts against the degradation of hazardous dyes.