Nano-synthesis of solid acid catalysts from waste-iron-filling for biodiesel production using high free fatty acid waste cooking oil

Abstract

AbstractWaste-iron-filling (WIF) served as a precursor to synthesize α-$${\text{Fe}}_{2} {\text{O}}_{3}$$ Fe 2 O 3 through the co-precipitation process. The α-$${\text{Fe}}_{2} {\text{O}}_{3}$$ Fe 2 O 3 was converted to solid acid catalysts of RBC500, RBC700, and RBC900 by calcination with temperatures of 500, 700 and 900 °C respectively and afterwards sulfonated. Among the various techniques employed to characterize the catalysts is Fourier transforms infrared spectrometer (FT-IR), X-ray diffraction (XRD and Scanning electron microscopy (SEM). Performance of the catalysts was also investigated for biodiesel production using waste cooking oil (WCO) of 6.1% free fatty acid. The XRD reveals that each of the catalysts composed of Al–$${\text{Fe}}_{2} {\text{O}}_{3} /{\text{SO}}_{4}$$ Fe 2 O 3 / SO 4 . While the FT-IR confirmed acid loading by the presence of $${\text{SO}}_{4}^{2 - }$$ SO 4 2 - groups. The RBC500, RBC700, and RBC900 possessed suitable morphology with an average particle size of 259.6, 169.5 and 95.62 nm respectively. The RBC500, RBC700, and RBC900 achieved biodiesel yield of 87, 90 and 92% respectively, at the process conditions of 3 h reaction time, 12:1 MeOH: WCO molar ratio, 6 wt% catalyst loading and 80 °C temperature. The catalysts showed the effectiveness and relative stability for WCO trans-esterification over 3 cycles. The novelty, therefore, is the synthesis of nano-solid acid catalyst from WIF, which is cheaper and could serve as an alternative source for the ferric compound.