The electro-oxidation of primary alcohols via a coral-shaped cobalt metal–organic framework modified graphite electrode in neutral media

Abstract

AbstractThe electro-oxidation of alcohols into corresponding aldehydes achieved enormous attention. However, numerous challenges remain in exploring catalytic systems with high conversion efficiency and selectivity. Considering the worldwide attention toward metal–organic frameworks (MOFs) as outstanding crystalline porous materials, many chemists have been encouraged to use them in organic transformations. In this study, a novel coral-shaped cobalt organic framework was grown onto the surface of a functionalized graphite electrode (Co-MOF/C) to fabricate an efficient modified electrode in the electro-oxidation alcohols. The modified Co-MOF/C electrode showed high stability, large surface area, rich pores, and good conductivity as a desirable water-stable working electrode for selective oxidation of alcohols into aldehydes in good to excellent yields under a diffusion-controlled process.