Ultra-small and highly dispersive iron oxide hydroxide as an efficient catalyst for oxidation reactions: a Swiss-army-knife catalyst

Abstract

AbstractUltra-small and highly dispersive (< 10 nm) iron oxide hydroxide is characterized by some methods. The compound is an efficient and stable catalyst for alcohol oxidation, organic sulfide oxidation, and epoxidation of alkenes in the presence of H2O2. The electrochemical oxygen-evolution reaction of the iron oxide hydroxide is also tested under acidic, neutral, and alkaline conditions. In the presence of the iron oxide hydroxide, excellent conversions (75–100%) and selectivities of substrates (92–97%), depending on the nature of the sulfide, were obtained. Benzylalcohols having electron-donating and-withdrawing substituents in the aromatic ring were oxidized to produce the corresponding aldehydes with excellent conversion (65–89%) and selectivity (96–100%) using this iron oxide hydroxide. The conversion of styrene and cyclooctene toward the epoxidation in the presence of this catalyst are 60 and 53%, respectively. Water oxidation for the catalysts was investigated at pH 2, 6.7, 12, and 14. The onset of OER at pH 14 is observed with a 475 mV overpotential. At 585 mV overpotential, a current density of more than 0.18 mA/cm2 and a turnover frequency of 1.5/h is observed. Operando high-resolution visible spectroscopy at pH 14, similar to previously reported investigations, shows that Fe(IV)=O is an intermediate for water oxidation.