Abstract
AbstractIn this study, the physicochemical properties of [NH3(CH2)5NH3]ZnCl4 crystals were investigated using X-ray diffraction (XRD), Fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis, and nuclear magnetic resonance (NMR). The crystals at 300 K had a monoclinic structure with C2/c space group and lattice constants are a = 21.4175 Å, b = 7.3574 Å, c = 19.1079 Å, β = 120.5190°, and Z = 8. Three endothermic peaks at 256, 390, and 481 K were observed in the DSC curve. From the single-crystal XRD patterns, powder XRD patterns, and optical microscopy results based on the temperature change, the phase transition and melting temperatures were determined to be 390 and 481 K, respectively. NMR studies indicated no change in 1H chemical shifts, but a change in the chemical shifts for C2, located between C1 and C3 of the cation at 340 K. Increase in molecular motion caused an increase in the spin–lattice relaxation time, T1ρ, at low spinning rates, under magic-angle spinning rate conditions. This crystal showed a minor change in the N−H···Cl hydrogen bond, related to the coordination geometry of the ZnCl4 anion.
Funder
National Research Foundation of Korea
NRF
Publisher
Springer Science and Business Media LLC
Reference36 articles.
1. Su, C. et al. Hybrid optical-electrical perovskite can be a ferroelastic semiconductor. CCS Chem. 3, 2021 (2021).
2. Xie, Y. et al. The soft molecular polycrystalline ferroelectric realized by the fluorination effect. J. Am. Chem. Soc. 142, 12486 (2020).
3. Fu, D.-W. et al. High-TC enantiometric ferroelectric based on homochiral dabco-derivatives (Dabco=1,4-Diazabicyclo[2.2.2.]octane. Angew. Chem. Int. Ed. 59, 17477 (2020).
4. Rao, C. N. R., Cheetham, A. K. & Thirumurugan, A. Hybrid inorganic-organic materials: A new family in condensed matter physics. J. Phys.: Condens. Matter 20, 83202 (2008).
5. Cheng, Z. & Lin, J. Layered organic–inorganic hybrid perovskites: structure, optical properties, film preparation, patterning and templating engineering. Cryst. Eng. Com. 12, 2646 (2010).
Cited by
10 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. A comprehensive study of crystal structure, UV–visible study, electric-dielectric properties of a recently developed Hybrid Material [(C6H5N2)2ZnCl4];Materials Research Bulletin;2024-11
2. Exploring the potential applications of lead-free organic–inorganic perovskite type [NH3(CH2)nNH3]MCl4 (n = 2, 3, 4, 5, and 6; M = Mn, Co, Cu, Zn, and Cd) crystals;Scientific Reports;2024-05-23
3. Investigation on the organic–inorganic hybrid crystal [NH2(CH3)2]2CuBr4: structure, phase transition, thermal property, structural geometry, and dynamics;Scientific Reports;2023-11-29
4. Hyper Thermostability and Liquid-Crystal-Like Properties of Designed α-Helical Peptide Nanofibers;The Journal of Physical Chemistry B;2023-09-26
5. Analysis of the Structure, Thermal, and Molecular Dynamics of Organic–Inorganic Hybrid Crystal at Phases IV, III, II, and I: [NH2(CH3)2]2CdBr4;ACS Omega;2023-09-08