Using thermokinetic methods to enhance properties of epoxy resins with amino acids as biobased curing agents by achieving full crosslinking

Abstract

AbstractFibre-reinforced polymers (FRPs) are used in numerous industrial sectors and contribute to reducing CO2 emissions due to their outstanding properties in lightweight design. However, sustainable alternatives must be developed since the matrix polymers utilised contain substances hazardous to health and the environment. In widely used epoxy resins, the curing agents are mainly critical. Using biomolecules instead of synthetic curing agents can significantly reduce composites' toxicity and petrol-based carbon content. This study considerably exceeds the thermo-mechanical properties of epoxies cured with amino acids described in the literature until now. It demonstrates competitive or even better properties than state-of-the-art epoxies cured with petrol-based amine curing agents. For instance, the tensile strength of arginine-cured epoxy is more than twice as high as reported before and 13.5% higher compared to the petrol-based reference. At the same time, a high elongation at break of over 6% was accomplished, making these polymers suitable as matrix materials in FRPs. Furthermore, the glass transition onset of up to 130 °C is sufficiently high for many applications. The key to success is the development of individual curing profiles based on thermokinetic analysis. The work provides the development and analysis of several biomolecule-cured epoxies with promising property spectra.