Abstract
AbstractPhotoinduced transitions between the solid, glass, and liquid states based on molecular photoswitches promise a wide variety of applications. Photoswitchable adhesives are representative examples and are expected to contribute to material recycling for a sustainable future in the era of composite materials due to strong bonding and on-demand photo-induced debonding with minimal damage to the adherents. Only a few molecular photoswitches are known to undergo these transitions, but recent progress, mainly with azobenzene, has been remarkable. Here, we review the photoinduced transitions of small molecules and polymers over approximately a decade and systematically discuss the molecular designs, mechanisms, applications, merits and demerits, and future challenges in each photoswitch and the whole field. We hope this review provides useful information, inspiration, and ideas for the development of this field and the expansion of its applications.
Funder
MEXT | Japan Society for the Promotion of Science
Ministry of Education, Culture, Sports, Science and Technology
MEXT | JST | Precursory Research for Embryonic Science and Technology
Publisher
Springer Science and Business Media LLC
Subject
Materials Chemistry,Polymers and Plastics