Free carbenes from complementarily paired alkynes
Author:
Funder
National Science Foundation
Publisher
Springer Science and Business Media LLC
Link
https://www.nature.com/articles/s41557-024-01550-9.pdf
Reference49 articles.
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3. Tornøe, C. W., Christensen, C. & Meldal, M. Peptidotriazoles on solid phase: [1,2,3]-triazoles by regiospecific copper(i)-catalyzed 1,3-dipolar cycloadditions of terminal alkynes to azides. J. Org. Chem. 67, 3057–3064 (2002).
4. Hein, J. E. & Fokin, V. V. Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(i) acetylides. Chem. Soc. Rev. 39, 1302–1315 (2010).
5. Larock, R. C. & Yum, E. K. Synthesis of indoles via palladium-catalyzed heteroannulation of internal alkynes. J. Am. Chem. Soc. 113, 6689–6690 (1991).
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1. Reactions of Electrophilic Allenoates [and Isocyanates/Isothiocyanates] with a 2-Alkynylpyridine via a Free Carbene Intermediate;Organic Letters;2024-09-10
2. Alkynes fuel free carbene formation;Nature Chemistry;2024-07
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