Complete chiral symmetry breaking of an amino acid derivative directed by circularly polarized light

Author:

Noorduin Wim L.,Bode Arno A. C.,van der Meijden Maarten,Meekes Hugo,van Etteger Albert F.,van Enckevort Willem J. P.,Christianen Peter C. M.,Kaptein Bernard,Kellogg Richard M.,Rasing Theo,Vlieg Elias

Publisher

Springer Science and Business Media LLC

Subject

General Chemical Engineering,General Chemistry

Reference23 articles.

1. Le Bel, J. A. Sur les relations qui existent entre les formulas atomiques de corps organiques et le pouvior rotatiore de leurs dissolutions. Bull. Soc. Chim. Fr. 22, 337–347 (1874).

2. Van't Hoff, J. H. Voorstel tot uitbreiding der tegenwoordig in de scheikunde gebruikte structuur-formules in de ruimte: benevens een daarmee samenhangende opmerking omtrent het verband tusschen optisch actief vermogen en chemische constitutie van organische verbindingen. Pamphlet, Utrecht, September 3 (1874).

3. Bailey, J. et al. Circular polarization in star-formation regions: implications for biomolecular homochirality. Science 281, 672–674 (1998).

4. Cronin, J. R. & Pizzarello, S. Enantiomeric excesses in meteoritic amino acids. Science 275, 951–955 (1997).

5. Balavoine, G., Moradpour, A. & Kagan, H. B. Preparation of chiral compounds with high optical purity by irradiation with circularly polarized light, a model reaction for the prebiotic generation of optical activity. J. Am. Chem. Soc. 96, 5152–5158 (1974).

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