Structure, Reactivity, and Density Functional Theory Analysis of the Six-Electron Reductant, [(C5Me5)2U]2(μ-η6:η6-C6H6), Synthesized via a New Mode of (C5Me5)3M Reactivity
Author:
Affiliation:
1. Contribution from the Departments of Chemistry, University of California, Irvine, California 92697-2025, and University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja0463886
Reference103 articles.
1. Synthesis and x-ray crystal structure of the first tris(pentamethylcyclopentadienyl)metal complex: (.eta.5-C5Me5)3Sm
2. Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M
3. Reaction Chemistry of Sterically Crowded Tris(pentamethylcyclopentadienyl)samarium1
4. The Trivalent Neodymium Complex [(C5Me5)3Nd] Is a One-Electron Reductant!
5. Synthesis and Structure of a Thermally Stable, Nonclassical, 7-Norbornadienyl Carbocation Obtained from (C5Me5)3Sm and CO
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