Glycine Enolates: The Large Effect of Iminium Ion Formation on α-Amino Carbon Acidity
Author:
Affiliation:
1. Department of Chemistry, University at Buffalo SUNY, Buffalo New York 14260-3000 Departamento de Química Física, Facultad de Química Universidad de Santiago 15706 Santiago de Compostela, Spain
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja016250c
Reference18 articles.
1. Electrophilic catalysis can explain the unexpected acidity of carbon acids in enzyme-catalyzed reactions
2. Biological Enolates: Generation and Stability of the Enolate of N-Protonated Glycine Methyl Ester in Water
3. Formation and Stability of Organic Zwitterions in Aqueous Solution: Enolates of the Amino Acid Glycine and Its Derivatives
4. Vitamin B6-catalyzed reactions of .alpha.-amino and .alpha.-keto acids: model systems
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