Tetranuclear Phosphide- and Phosphinidene-Bridged Derivatives of the Diphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2Me)(CO)2]
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
2. Instituto Nacional del Carbón, CSIC, Francisco Pintado Fe 26, E-33011 Oviedo, Spain
Funder
Ministerio de Economía y Competitividad
Consejo Superior de Investigaciones Científicas
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic503076x
Reference63 articles.
1. Mild P–P Bond Cleavage in the Methyldiphosphenyl Complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2Me)(CO)2] To Give Novel Phosphide-Bridged Trinuclear Derivatives
2. Übergangsmetall‐substituierte Diphosphene, XX 1) Synthese und Eigenschaften des Tetrahedrans [(η 5 ‐C 5 Me 5 )(CO) 2 FeP–P t Bu]Fe 2 (CO) 6 und der metallierten 1,3‐Diphospha‐2‐propanone [(η 5 ‐C 5 Me 5 )(CO) 2 Fe–PC(O)–PR]Fe 2 (CO) 6 [R = t Bu, 2,4,6‐(CF 3 ) 3 C 6 H 2 ]
3. Activation of P4 and P2 by Transition Metal Complexes at Room Temperature
4. Mild P4 Activation To Give an Anionic Diphosphorus Complex with a Dual Binding Ability at a Single P Site
5. Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(CO)2(μ-κ2:κ2-P2)]− Toward ER3X Electrophiles (E = C to Pb): Insights into the Multisite Donor Ability and Dynamics of the P2 Ligand
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