Isodiiodomethane Is the Methylene Transfer Agent in Cyclopropanation Reactions with Olefins Using Ultraviolet Photolysis of Diiodomethane in Solutions: A Density Functional Theory Investigation of the Reactions of Isodiiodomethane, Iodomethyl Radical, and Iodomethyl Cation with Ethylene
Author:
Affiliation:
1. Contribution from the Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong S. A. R., P. R. China, and Department of Chemistry, Beijing Normal University, Beijing 100875, P. R. China
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja003090g
Reference59 articles.
1. A New Synthesis of Cyclopropanes1
2. Photolysis of Methylene Iodide in the Presence of Olefins
3. Photochemistry of alkyl halides. 6. gem-Diiodides. A convenient method for the cyclopropanation of olefins
4. Photochemistry of alkyl halides—VII
5. Photobehavior of alkyl halides in solution: radical, carbocation, and carbene intermediates
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