Surface Organometallic Chemistry: Understanding the Multistep Process of Silica-Mediated Synthesis of Various Osmium Carbonyl Clusters from Supported α-[Os(CO)3Cl2]2
Author:
Affiliation:
1. Dipartimento di Chimica Inorganica, Metallorganica e Analitica and Centro CNR, Università di Milano, Via G. Venezian 21, 20133 Milano, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om970590i
Reference50 articles.
1. Surface-mediated organometallic synthesis: preparation of osmium carbonyl clusters [Os5C(CO)14]2- and [Os10C(CO)24]2- on the basic magnesium oxide surface
2. Surface-mediated organometallic synthesis: high-yield preparations of iridium, rhodium, ruthenium, and osmium complexes {Ir(CO)3Cl}n, [Rh(CO)2Cl]2, [Ru(CO)3Cl2]2, [Os(CO)3Cl2]2, [Ir4(CO)12], and [Rh6(CO)16] by reductive carbonylation, under mild conditions, of silica-supported metal chlorides
3. Surface organometallic chemistry: Reductive carbonylation of silica-supported RuCl3 · 3H2O
4. Surface-mediated synthesis of metal clusters
5. Surface-mediated organometallic synthesis: formation of [Rh12(CO)30]2- and [Rh5(CO)15]- on .gamma.-alumina and on magnesia
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