NMR and INS Line Shapes of Transition Metal Hydrides in the Presence of Coherent and Incoherent Dihydrogen Exchange-Reference-Cited by-同舟云学术

NMR and INS Line Shapes of Transition Metal Hydrides in the Presence of Coherent and Incoherent Dihydrogen Exchange

Published:1998-07-28 Issue:31 Volume:120 Page:7929-7943
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Limbach Hans-Heinrich¹,Ulrich Stefan¹,Gründemann Stephan¹,Buntkowsky Gerd¹,Sabo-Etienne Sylviane¹,Chaudret Bruno¹,Kubas Gregory J.¹,Eckert Jürgen¹

Affiliation:

1. Contribution from the Institut für Organische Chemie der Freien Universität Berlin, Takustrasse 3, D-14195 Berlin, Germany, the Laboratoire de Chimie de Coordination du CNRS (UP 8241), 205, route de Narbonne, F-31077 Toulouse-Cedex, France, and LANSCE, Los Alamos National Laboratory, Los Alamos, Mail Stop H805, New Mexico 87545

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja962903r

Reference78 articles.

1. Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand

2. Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

3. Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO)3(PR3)2H2 where R = isopropyl and cyclopentyl

4. An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3

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