Diastereoselective Formation of a New Palladacycle and Organic Compounds Derived from Vinylcarbenoids as Side Products in the Synthesis of 5-Pallada-trans-tricyclo[4.1.0.02,4]heptanes from Acceptor-Substituted Cyclopropenes

Author:

Hashmi A. Stephen K.1,Grundl Marc A.1,Bats Jan W.1

Affiliation:

1. Institut für Organische Chemie der Johann Wolfgang Goethe-Universität, Marie-Curie-Strasse 11, D-60439 Frankfurt am Main, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference42 articles.

1. For reviews see:  (a) Binger, P.; Büch, H. M.Top. Curr. Chem.1987,135, 77−151. (b) Ohta, T.; Takaya, H. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon:  Oxford, U.K., 1991; Vol. 5, pp 1185−1205. (c) Schmidt, T. InCarbocyclic Three- and Four-Membered RingCompounds(Houben-Weyl); de Meijere, A., Ed.; Thieme:  Stuttgart, Germany, 1997; Vol. E 17a, pp 213−255.

2. New tantalum ylide complexes: crystal and molecular structure of (.eta.5-C5Me5)Cl4Ta(CH2:PMePh2) containing a neutral phosphorus ylide

3. Cyclopropene als Komplexliganden: Fe2(CO)9-induzierte Ringöffnung eines Spirocyclopropens und reversible CO-Addition an den Vinylcarben-Liganden

4. Ring-opening metathesis polymerization (ROMP) of norbornene by a Group VIII carbene complex in protic media

5. Reactions of a Chelated Cyclopentadienylcobalt(I) Complex with 3,3-Disubstituted Cyclopropenes:  Formation of Isoprene, Vinylcarbene, and 1-Phosphadiene Ligands at the Metal

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