Cationic Zirconium Hydrides Supported by an NNNN-Type Macrocyclic Ligand: Synthesis, Structure, and Reactivity
Author:
Affiliation:
1. Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52056 Aachen, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic301880z
Reference113 articles.
1. Hydrido complexes of zirconium I. Preparation
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3. Preparation and structural characterization of early-transition-metal hydrides. [(.eta.5-C5H4CH3)2ZrH(.mu.-H)]2, a binuclear zirconium hydride complex
4. Synthesis, x-ray structure and electrochemical study of [{.eta.5-C5H4C(CH3)3}2ZrH(.mu.-H)]2. Identification of the [{.eta.5-C5H4C(CH3)3}]2ZrH2 anion radical by EPR spectroscopy
5. Synthesis, characterization, and chemical reactivity of zirconium dihydride [(C5H4R)2Zr(.mu.-H)H]2 (R = SiMe3, CMe3). H/D exchange reactions of anionic species [(C5H4R)2ZrH2]-. X-ray crystal structure of [(C5H4SiMe3)2Zr(.mu.-H)H]2
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