Structure−Reactivity Relationships and Intrinsic Reaction Barriers for Nucleophile Additions to a Quinone Methide: A Strongly Resonance-Stabilized Carbocation-Reference-Cited by-同舟云学术

Structure−Reactivity Relationships and Intrinsic Reaction Barriers for Nucleophile Additions to a Quinone Methide: A Strongly Resonance-Stabilized Carbocation

Published:2000-02-10 Issue:8 Volume:122 Page:1664-1674
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Richard John P.¹,Toteva Maria M.¹,Crugeiras Juan¹

Affiliation:

1. Contribution from the Department of Chemistry, University at Buffalo, SUNY, Buffalo New York 14260-3000, and the Departamento de Química Física, Facultad de Química, Universidad de Santiago, 15706 Santiago de Compostela, Spain

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9937526

Reference71 articles.

1. Formation of Carbon-Carbon Bonds via Quinone Methide-Initiated Cyclization Reactions

2. Determination of the pKa Values for the Mitomycin C Redox Couple by Titration, pH Rate Profiles, and Nernst-Clark Fits. Studies of Methanol Elimination, Carbocation Formation, and the Carbocation/Quinone Methide Equilibrium

3. Thermal Decomposition of Chroman. Reactivity of o-Quinone Methide

4. The remarkable nucleophilic reactivity of molybdate

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