Detection of Unusual Reaction Intermediates during the Conversion of W(N2)2(dppe)2 to W(H)4(dppe)2 and of H2O into H2
Author:
Affiliation:
1. Department of Chemistry, University of York, Heslington, York , U.K. YO10 5DD
2. Department of Safety of Medicines, AstraZeneca, Alderley Park, Macclesfield, Cheshire, U.K. SK10
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja302202q
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4. Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO)3(PR3)2H2 where R = isopropyl and cyclopentyl
5. Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand
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