Fe(TPA)-Catalyzed Alkane Hydroxylation. Metal-Based Oxidation vs Radical Chain Autoxidation
Author:
Affiliation:
1. Contribution from the Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja9542303
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3. Cobalt-induced activation of hydrogen peroxide for the direct ketonization of methylenic carbons [c-C6H12 .fwdarw. c-C6H10(O)], the oxidation of alcohols and aldehydes, and the dioxygenation of aryl olefins and acetylenes
4. Iron(II)/hydroperoxide (fenton reagent)-induced activation of dioxygen for (A) the direct ketonization of methylenic carbon and (B) the dioxygenation of cis-stilbene
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