Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double Bonds-Reference-Cited by-同舟云学术

Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R2C═U═O]2+ Analogue of the [O═U═O]2+ Uranyl Ion (R = Ph2PNSiMe3), and Comparison of the Nature of UIV═C, UV═C, and UVI═C Double Bonds

Published:2012-06-07 Issue:24 Volume:134 Page:10047-10054
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Mills David P.¹,Cooper Oliver J.¹,Tuna Floriana²,McInnes Eric J. L.²,Davies E. Stephen¹,McMaster Jonathan¹,Moro Fabrizio¹,Lewis William¹,Blake Alexander J.¹,Liddle Stephen T.¹

Affiliation:

1. School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, U.K.

2. EPSRC National UK EPR Facility, School of Chemistry and Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja301333f

Reference79 articles.

1. Di- and Polymetallic Heteroatom Stabilized (Fischer) Metal Carbene Complexes

2. High Oxidation State Multiple Metal−Carbon Bonds

3. A tribute to Frederick Nye Tebbe. Lewis acid stabilized alkylidyne, alkylidene, and imides of 3d early transition metals

4. Lanthanide alkylidene and imido complexes

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