Diastereoselective Intermolecular Rhodium-Catalyzed [4 + 2 + 2] Carbocyclization Reactions: Computational and Experimental Evidence for the Intermediacy of an Alternative Metallacycle Intermediate
Author:
Affiliation:
1. Department of Chemistry and School of Informatics, Indiana University, Bloomington, Indiana 47405
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja043521l
Reference9 articles.
1. Rhodium(I)-Catalyzed Asymmetric Intramolecular Pauson−Khand-Type Reaction
2. Diastereoselective metal-catalyzed [4 + 2 + 2] carbocyclization reactions utilizing a rhodium N-heterocyclic carbene (NHC) complex: the first example of a rhodium NHC-catalyzed [m+n+o] carbocyclization
3. Regio- and Diastereoselective Tandem Rhodium-Catalyzed Allylic Alkylation/Pauson−Khand Annulation Reactions
4. Dicobaltoctacarbonyl-alkyne complexes as intermediates in the synthesis of bicyclo[3.3.0]octenones for the synthesis of coriolin and hirsutic acid
5. Highly Enantioselective Catalytic Pauson−Khand Type Formation of Bicyclic Cyclopentenones
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