Synthesis and X-ray Structures of Elusive Imine/Oxime-Type Organocobalt B12 Complexes. NMR Study Suggesting Steric Strain within the Axially Ligated Benzimidazole
Author:
Affiliation:
1. Department of Chemistry, Emory University, Atlanta, Georgia 30322, and Dipartimento di Scienze e Tecnologie Chimiche e dei Biosistemi, Università di Siena, Pian dei Mantellini 44, 53100 Siena, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic961105z
Reference47 articles.
1. How a Protein Binds B 12 : A 3.0 Å X-Ray Structure of B 12 -Binding Domains of Methionine Synthase
2. How coenzyme B12 radicals are generated: the crystal structure of methylmalonyl-coenzyme A mutase at 2 å resolution
3. Coenzyme B12 Is Coordinated by Histidine and Not Dimethylbenzimidazole on Methylmalonyl-CoA Mutase
4. Organocobalt complexes with exceptionally poor electron-donating alkyl groups. Extension and quantitation of the relationship between structure and NMR spectra in B12 models
5. Organocobalt B12 models: axial ligand effects on the structural and coordination chemistry of cobaloximes
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