Ab Initio Study of the Effect of Fluorination upon the Structure and Configurational Stability of α-Sulfonyl Carbanions: The Role of Negative Hyperconjugation
Author:
Affiliation:
1. Contribution from the Institut für Organische Chemie, Rheinisch-Westfälische Technische Hochschule Aachen, Professor-Pirlet-Strasse 1, 52056 Aachen, Germany
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja953034t
Reference104 articles.
1. Oae, S.; Uchida, Y. InThe Chemistry of Sulphones and Sulphoxides; Patai, S., Rappoport, Z., Stirling, C. J. M., Eds.; John Wiley: New York, 1988; p 583.
2. Röntgen-Strukturuntersuchung von [α-(Phenylsulfonyl)benzyllithium-Tetramethylethylendiamin]2: Chiralität eines α-Sulfonyl- „Carbanions”
3. Lithium-koordinierte α-Sulfonyl-Carbanionen: Synthese und Röntgen-Strukturanalyse von [CH2(SO2C6H5)Li(tmeda)]2
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