On the Importance of Prereactive Complexes in Molecule−Radical Reactions:  Hydrogen Abstraction from Aldehydes by OH

Author:

Alvarez-Idaboy J. R.1,Mora-Diez Nelaine1,Boyd Russell J.1,Vivier-Bunge Annik1

Affiliation:

1. Contribution from the Laboratorio de Química Computacional y Teórica, Facultad de Química, Universidad de La Habana, Habana 10400, Cuba, Instituto Mexicano del Petróleo, 07730 México, D.F., México, Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada B3H 4J3, and Departamento de Química, Universidad Autónoma Metropolitana, Iztapalapa, 09340 México, D.F., México

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference34 articles.

1. Finlayson-Pitts, B. J. ; Pitts, N. Atmospheric Chemistry:  Fundamentalsand Experimental Techniques; Wiley-Interscience:  New York, 1986.

2. The NIST Chemical Kinetics Data Base, NIST Standard Reference Database; U.S. Dept. of Commerce, Technology Administration, National Institute of Standards and Technology:  Gaithersburg, MD, 17-2Q98.

3. Rate constants for the reaction of hydroxyl radicals with acetaldehyde from 244–528 K

4. Kinetic and mechanistic studies of the reaction of hydroxyl radicals with acetaldehyde over an extended temperature range

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