Unraveling the Origin of Regioselectivity in Rhodium Diphosphine Catalyzed Hydroformylation. A DFT QM/MM Study-Reference-Cited by-同舟云学术

Unraveling the Origin of Regioselectivity in Rhodium Diphosphine Catalyzed Hydroformylation. A DFT QM/MM Study

Published:2001-07-17 Issue:31 Volume:123 Page:7630-7637
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Carbó Jorge J.¹,Maseras Feliu¹,Bo Carles¹,van Leeuwen Piet W. N. M.¹

Affiliation:

1. Contribution from the Unitat de Química Física, Edifi C.n, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona, Spain, Departament de Química Física i Inorgànica and Institut d'Estudis Avançats, Universitat Rovira i Virgili, Pl. Imperial Tarraco, 1, 43005 Tarragona, Spain, and Institute for Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0101678

Reference54 articles.

1. Electron Withdrawing Substituents on Equatorial and Apical Phosphines Have Opposite Effects on the Regioselectivity of Rhodium Catalyzed Hydroformylation

2. The mechanism of phosphine-modified rhodium-catalyzed hydroformylation studied by CIR-FTIR

3. A study of the mechanism of rhodium/phosphine-catalyzed hydroformylation: use of 1,1′-bis(diarylphosphino)ferrocene ligands

4. Electronically Dissymmetric DIPHOS Derivatives Give Higher n:i Regioselectivity in Rhodium-Catalyzed Hydroformylation Than Either of Their Symmetric Counterparts

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