Synthesis, Neutron Structure, and Reactivity of the Bis(dihydrogen) Complex RuH2(η2-H2)2(PCyp3)2 Stabilized by Two Tricyclopentylphosphines-Reference-Cited by-同舟云学术

Synthesis, Neutron Structure, and Reactivity of the Bis(dihydrogen) Complex RuH2(η2-H2)2(PCyp3)2 Stabilized by Two Tricyclopentylphosphines

Published:2005-11-19 Issue:50 Volume:127 Page:17592-17593
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Grellier Mary¹,Vendier Laure¹,Chaudret Bruno¹,Albinati Alberto¹,Rizzato Silvia¹,Mason Sax¹,Sabo-Etienne Sylviane¹

Affiliation:

1. Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 04, France, Department of Structural Chemistry (DCSSI), University of Milan, 21, Via G. Venezian, 20133 Milan, Italy, and Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, 38042 Grenoble Cedex 9, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja055126g

Reference24 articles.

1. Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand

2. Metal Dihydrogen and σ-Bond Complexes

3. C–H and H–H bond activation; dissociative vs. nondissociative binding to iridium

4. Considered as onium ions. 31. Protonated hydronium dication, H4O2+. Hydrogen-deuterium exchange of Dd2H17 O+ in HF-SbF5 and DH217O+ in DF-SbF5 and theoretical calculations

5. 16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2tPh)2+ and 18-electron Ir(H)2(H2)2(PBu2tPh)2+: fluxionality and H/D exchange as independent processes

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