Mechanism of Nitrogenase H2 Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects-Reference-Cited by-同舟云学术

Mechanism of Nitrogenase H2 Formation by Metal-Hydride Protonation Probed by Mediated Electrocatalysis and H/D Isotope Effects

Published:2017-09-15 Issue:38 Volume:139 Page:13518-13524
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Khadka Nimesh¹,Milton Ross D.²^ORCID,Shaw Sudipta¹,Lukoyanov Dmitriy³,Dean Dennis R.⁴,Minteer Shelley D.²^ORCID,Raugei Simone⁵,Hoffman Brian M.³^ORCID,Seefeldt Lance C.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322, United States

2. Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States

3. Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States

4. Department of Biochemistry, Virginia Tech, Blacksburg, Virginia 24061, United States

5. Pacific Northwest National Laboratory, Richland, Washington 99352, United States

Funder

Basic Energy Sciences

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.7b07311

Reference27 articles.

1. On reversible H2 loss upon N2 binding to FeMo-cofactor of nitrogenase

2. Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

3. Identification of a Key Catalytic Intermediate Demonstrates That Nitrogenase Is Activated by the Reversible Exchange of N2 for H2

4. Photoinduced Reductive Elimination of H2 from the Nitrogenase Dihydride (Janus) State Involves a FeMo-cofactor-H2 Intermediate

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