Understanding the Unusual Reduction Mechanism of Pd(II) to Pd(I): Uncovering Hidden Species and Implications in Catalytic Cross-Coupling Reactions
Author:
Affiliation:
1. Johnson Matthey, Orchard Road, Royston SG8 5HE, United Kingdom
2. Institute of Organic Chemistry, RWTH Aachen, Landoltweg 1, 52074 Aachen, Germany
3. Johnson Matthey, 2001 Nolte Drive, West Deptford, New Jersey 08066, United States
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.7b01110
Reference45 articles.
1. Understanding Precatalyst Activation in Cross-Coupling Reactions: Alcohol Facilitated Reduction from Pd(II) to Pd(0) in Precatalysts of the Type (η3-allyl)Pd(L)(Cl) and (η3-indenyl)Pd(L)(Cl)
2. Capture of Reactive Monophosphine-Ligated Palladium(0) Intermediates by Mass Spectrometry
3. Insight into the Efficiency of Cinnamyl-Supported Precatalysts for the Suzuki–Miyaura Reaction: Observation of Pd(I) Dimers with Bridging Allyl Ligands During Catalysis
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