Interpreting “Acidity” as a Global Property Controlling Comonomer Reactivity in Olefin Polymerization
Author:
Affiliation:
1. Dipartimento di Chimica e Biologia, Università degli Studi di Salerno, via Giovanni Paolo II, 132, 84084 Fisciano, Italy
2. Dipartimento di Scienza ed Alta Tecnologia, Università degli Studi dell’Insubria, via Valleggio 11, 22100 Como, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400076k
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3. Role of the Metal Center in the Ethylene Polymerization Promoted by Group 4 Complexes Supported by a Tetradentate [OSSO]-Type Bis(phenolato) Ligand
4. Highly Electrophilic Olefin Polymerization Catalysts. Quantitative Reaction Coordinates for Fluoroarylborane/Alumoxane Methide Abstraction and Ion−Pair Reorganization in Group 4 Metallocene and “Constrained Geometry” Catalysts J. Am. Chem. Soc. 1998, 120, 1772−1784
5. Metal-Alkyl Group Effects on the Thermodynamic Stability and Stereochemical Mobility of B(C6F5)3-Derived Zr and Hf Metallocenium Ion-Pairs
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