Kinetic Analysis of “Living” Polymerization Systems Exhibiting Slow Equilibria. 4. “Dissociative” Mechanism of Group Transfer Polymerization and Generation of Free Ions in Cationic Polymerization
Author:
Affiliation:
1. Institut für Physikalische Chemie, Johannes Gutenberg-Universität Mainz, D-55099 Mainz, Germany
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ma950928p
Reference20 articles.
1. Kinetic Analysis of "Living" Polymerization Processes Exhibiting Slow Equilibria. 1. Degenerative Transfer (Direct Activity Exchange between Active and "Dormant" Species). Application to Group Transfer Polymerization
2. Kinetic Analysis of "Living" Polymerization Processes Exhibiting Slow Equilibria. 2. Molecular Weight Distribution for Degenerative Transfer (Direct Activity Exchange between Active and "Dormant" Species) at Constant Monomer Concentration
3. Kinetic Analysis of “Living” Polymerization Systems Exhibiting Slow Equilibria. 3. “Associative” Mechanism of Group Transfer Polymerization and Ion Pair Generation in Cationic Polymerization
4. Mechanistic studies of group transfer polymerization. Silyl group exchange studies
5. Bimodal Molecular Weight Distribution in Carbocationic Systems with Free Ions and Ion Pairs of Equal Reactivities but Different Lifetimes
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