Defluorination of Perfluoropropene Using Cp*2ZrH2 and Cp*2ZrHF: A Mechanism Investigation from a Joint Experimental−Theoretical Perspective-Reference-Cited by-同舟云学术

Defluorination of Perfluoropropene Using Cp*2ZrH2 and Cp*2ZrHF: A Mechanism Investigation from a Joint Experimental−Theoretical Perspective

Published:2004-04-06 Issue:17 Volume:126 Page:5647-5653
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Clot Eric¹,Mégret Claire¹,Kraft Bradley M.¹,Eisenstein Odile¹,Jones William D.¹

Affiliation:

1. Contribution from the Laboratoire de Structure et Dynamique des Systèmes Moléculaires et Solides (UMR 5636), Case Courrier 14, Université Montpellier 2, 34095 Montpellier Cedex 5, France, and Department of Chemistry, University of Rochester, Rochester, New York 14627

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0499243

Reference43 articles.

1. Aliphatic and Aromatic Carbon−Fluorine Bond Activation with Cp*2ZrH2: Mechanisms of Hydrodefluorination

2. Mechanism of Vinylic and Allylic Carbon−Fluorine Bond Activation of Non-Perfluorinated Olefins Using Cp*2ZrH2

3. Effect of polyfluorination on ring inversion barriers for cyclooctatetraenes. Transition-metal compounds of unsaturated, polyfluorinated cycloaliphatics. Crystal and molecular structures of [Fe(.eta.-C5R5)(.eta.1-heptafluorocycloocta-1,3,5,7-tetraenyl)(CO)2] (R = H, Me), {[Fe(.eta.-C5H5)(CO)2]2(.mu.2-(1.eta.,5.eta.)-hexafluorocycloocta-1,3,5,7-tetraenediyl)], and [Mn((3.eta.)-heptafluorotricyclo[4.2.0.02,5]octa-3,7-dienyl)(CO)5]

4. Deprotonation of the Transition Metal Hydride (η5-C5Me5)(PMe3)IrH2. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η5-C5Me5)(PMe3)Ir(H)(Li)

5. The Reactivity of Metal-Metal Bonds. II. The Tin-Manganese Bond

Cited by 96 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Elucidating the Key Factors in Hydroamination and Defluoroamination Competitions: A DFT Analysis of Reaction between α‐(Trifluoromethyl)styrene and 2‐Pyridones;European Journal of Organic Chemistry;2024-04-23

2. From the Felkin‐Anh Rule to the Grignard Reaction: an Almost Circular 50 Year Adventure in the World of Molecular Structures and Reaction Mechanisms with Computational Chemistry**;Israel Journal of Chemistry;2022-02

3. Application of Industrially Relevant HydroFluoroOlefin (HFO) Gases in Organic Syntheses;Synthesis;2021-06-28

4. Fluorocarbon Refrigerants and their Syntheses: Past to Present;Chemical Reviews;2020-08-18

5. Copolymerization of Ethylene and Vinyl Fluoride by Self-Assembled Multinuclear Palladium Catalysts;Polymers;2020-07-19