Kinetic Study on Michael-Type Reactions of β-Nitrostyrenes with Cyclic Secondary Amines in Acetonitrile: Transition-State Structures and Reaction Mechanism Deduced from Negative Enthalpy of Activation and Analyses of LFERs

Author:

Um Ik-Hwan1,Kang Ji-Sun1,Park Jong-Yoon1

Affiliation:

1. Department of Chemistry and Division of Nano Sciences and ‡Department of Science Education, Ewha Womans University, Seoul 120-750, Korea

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference71 articles.

1. aSmith, M. B. and March, J.March’s Advanced Organic Chemistry,5th ed.Wiley-Interscience:New York, 2001; p976.

2. bLowry, T. H. and Richardson, K. S.Mechanism and Theory in Organic Chemistry,3rd ed.Harper Collins Publishers:New York, 1987; p622.

3. cCarey, F. A. and Sundberg, R. J.Advanced Organic Chemistry Part B: Reactions and Synthesis,3rd ed.Plenum Press:New York, 1990; pp39–46.

4. A Redox-Reconfigurable, Ambidextrous Asymmetric Catalyst

5. Refined Transition-State Models for Proline-Catalyzed Asymmetric Michael Reactions under Basic and Base-Free Conditions

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