Theoretical and Experimental Evidence for SN2 Transition States in Oxidative Addition of Methyl Iodide to cis-[M(CO)2I2]- (M = Rh, Ir)
Author:
Affiliation:
1. Department of Chemistry, University of Sheffield Sheffield, S3 7HF, England Hull Research and Technology Centre, BP Chemicals Ltd Salt End, Hull, HU12 8DS, England
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja952952o
Reference20 articles.
1. Mechanistic Pathways in the Catalytic Carbonylation of Methanol by Rhodium and Iridium Complexes
2. Mechanistic studies on rhodium-catalyzed carbonylation reactions: spectroscopic detection and reactivity of a key intermediate, [MeRh(CO)2I3]-
3. Mechanistic studies of oxidative addition to low-valent metal complexes. Stereochemistry at carbon in addition of alkyl halides to iridium(I)
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