Selective and Reversible Base-Induced Elimination of a Ruthenium Dithioether Yields a Vinyl Metallosulfonium Complex
Author:
Affiliation:
1. Department of Chemistry, University of Louisville, 2320 South Brook Street, Louisville, Kentucky 40292, United States
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic300983x
Reference43 articles.
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2. Cobalt(ii) and cobalt(iii) complexes of thioether-containing hexadentate pyrazine amide ligands: C–S bond cleavage and cyclometallation reaction
3. C–H Activation of co-ordinated crowns thioethers: deprotonation and ring-opening of [M([9]aneS3)2]3+(M = Co, Rh, Ir). Crystal structure of [Rh(H2CCHS(CH2)2S(CH2)2S)([9]aneS3)](PF6)2([9]aneS3= 1,4,7-trithiacyclononane)
4. Base-Induced Fragmentation of a Macrocyclic Thioether at an (Arene)ruthenium(II) Center. Generation of η1(S)-Ethenethiolate and η2(C,S)-Thioacetaldehyde
5. Syntheses and Single-Crystal X-ray Diffraction Studies of Acyclic and Macrocyclic Aza Dithiolate (NS2) Complexes of (Arene)ruthenium(II). Thiolate Alkylation, Base-Promoted Hydroalkylation, and Protonation Reactions
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