Thermally Stable Dialkylzirconocenes with β-Hydrogens. Synthesis and Diastereoselectivity
Author:
Affiliation:
1. Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0102910
Reference20 articles.
1. Index
2. Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts
3. Preparation of doubly-silylene-bridged zirconocene alkyl complexes, Me2Si)2{η5-C5H2-4-CHMe2}{η5-C5H-3,5-(CHMe2)2}ZrR2 (RCH3, CH2Ph) and investigations of their activity in 1-pentene polymerization. Molecular structure of (Me2Si)2{η5-C5H2-4-CHMe2}{η5-C5H-3,5- (CHMe2)2}Zr(CH2Ph)2
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2. Stereocontrolled monoalkylation of mixed-ring complex CpCp′ZrCl2 (Cp′ = 1-neomenthyl-4,5,6,7-tetrahydroindenyl) by lithium, magnesium and aluminum alkyls;Journal of Organometallic Chemistry;2013-02
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