Anti-Selective Epoxidation of Methyl α-Methylene-β-tert-butyldimethylsilyloxycarboxylate Esters. Evidence for Stereospecific Oxygen Atom Transfer in a Nucleophilic Epoxidation Process-Reference-Cited by-同舟云学术

Anti-Selective Epoxidation of Methyl α-Methylene-β-tert-butyldimethylsilyloxycarboxylate Esters. Evidence for Stereospecific Oxygen Atom Transfer in a Nucleophilic Epoxidation Process

Published:2009-04-27 Issue:11 Volume:11 Page:2437-2440
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Švenda Jakub¹,Myers Andrew G.¹

Affiliation:

1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol900665a

Reference29 articles.

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4. Synthesis of [n]polynorbornanes with differing edge substitution: a new class of regioselectively addressable frameworkThe term RAFT has been coined to describe such frameworks; RAFT is an acronym for Regioselectively Addressable Functionalised Template.1

5. Although we have successfully used anhydrous solid potassiumtert-butoxide in several experiments, for convenience we typically employ a 1.0 M stock solution of base in THF, prepared from the anhydrous solid (see theSupporting Information).

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